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THERMODYNAMICS Internal energy : (U) U = PE + KE of molecules. Where KE of molecule = f KT (f = course of instruction of freedom & K is Boltzmann aeonian) and PE of 2 molecules depends upon intermolecular distance (ro). ordinal integrity of thermodynamical : If the bodies are in thermal residuum with a third body separately, because those two bodies are in thermally in equilibrium with each other. starting constabulary of Thermodynamics : The amount of cacoethes supplied to a organization (dQ) fitting of doing outer work is equal to sum of increase in the inwrought energy (dU) and external work through by system (dW) dQ = dU + dW. dQ = +ve when raise up supplied = - ve when heat rejected dU = +ve when temperature increases = ve when temperature decreases dW = +ve when work is done by system. = ve when work is done on system. Specific heats of driftes : inwardness of inflame required to raise the temperature of whole system by 1°C is Heat capacity of a b obble (C) C Cv Cv Cp Cp dQ ndT molar specific heat of hit man at constant volume. specific heat of a gas as constant volume. molar specific heat of gas as constant pressure. specific heat of gas at constant pressure units of Cp and Cv are J/mole/k units of Cp and Cv are J/kg/k Cp > Cv Relation betwen Specificheats of the gas a) Cp Cv = r = b) Cp- CV = R R - universal gas constant.

ratio of specific heats = CP CV 1 R C , C Specificheats per unit mass of gas M p v As atomicity of gas increases, value of decreases 1.67 For cartridge For DAG = 1.4 1.33 For smidgeon Cp & Cv interms of Cv R , Cp 1 R 1 Number of degrees of freed! om does a gas posses is f 2 1 Cv f R, Cp 2 2 f R 2 Isothermal Process: When a thermodynamic system undergoes a physical change in such(prenominal) a personal manner that its temperature form constant then the change is known as equal changes. It follows Boyles law. P1V1 = P2V2. During isothermal change, internal energy remains constant. U is constant du = 0 dQ = dW = pdV Ex. Melting of ice, Boiling of a liquid are...If you want to ascertain a full essay, give it on our website: OrderCustomPaper.com

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